I am a bit ahead of you I suppose but I don't do math in my head. Pencil and paper are cheap and your phone has a calculator for big numbers.
Really, plumbing and everything else in life is all about the details. Deburring copper before sweating, using water soluble flux, the right type and amount of PVC glue, etc...
Then there are the tricks of the trade that make installation go more quickly. Having the right tools for the job is a big deal as well. Propex expansion fittings are so much better than the crimp but the power expansion tool cost $400.
As far as I am concerned, a good healthy fear of screwing up is all you need. Double check your calculations and your finished work and you will be ok. You will screw up every once in a while and it will be painful but if you take pride in your work, you will learn from those mistakes and not repeat them.