you have enough pressure., close off the other radiators flow., then bleed the air out of the up stairs radiator.... I would add a small pump, but it's probably not feasible...., So if it's in the budget., get a Circulating pump with MORE HEAD PRESSURE, and add an Expansion TANK.
It its in the basement and traveling to the 3rd floor., you're losing at least 15 psi just from height. So you have to make sure water is flowing thru the radiator., so if you lower the flow to the others' it will boost the flow to that one on the 3rd floor...