My guess, and that is all it is, is that Calfire is some type of governmental agency that sets standards for fire protection/prevention. I know that in my area, rural businesses have to have a large tank that is kept filled with water as a source in case of a fire at the business. Maybe this is something similar?
Anyway, I have seen 2 1/2" Sch 80 in both PVC and CPVC. Other than the somewhat lower flow rate because of the recuced ID due to the thicker pipe wall, I don't see any reason that it couldn't be used on the siphon side of the pump. What the enforcing agency would have to say, I have no idea. You probably already know this, but Sch 40 pipe & fittings and Sch 80 pipe & fittings are interchangeable.
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